Synthesis Structural And Electronic Properties And Reactivity Of Group 5 Metal Complexes Incorporating The Redox Active Ono Ligand Platform
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Synthesis, Structural and Electronic Properties, and Reactivity of Group 5 Metal Complexes Incorporating the Redox-active [ONO] Ligand Platform
Author | : Steven Paul Hananouchi |
Publisher | : |
Total Pages | : 67 |
Release | : 2014 |
Genre | : |
ISBN | : 9781303814730 |
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This thesis describes the synthesis, electronic and structural properties, and reactivity of Group 5 metal complexes incorporating the [ONO] ligand platform. A study of the electronic and structural properties of the Group 5 metal complexes incorporating the [ONO] ligand is performed. Once the electronic properties of the complexes are known, the reactivity of the complexes is compared. Chapter 1 describes a brief history of redox-active ligands. The previously published results of redox-active ligands acting as an electron source are discussed. In Chapter 2, the synthesis and electronic and structural properties of metal dichlorides and trichlorides of Group 5 metal complexes incorporating the [ONO] ligand and comparing the metal-ligand cooperativity are performed. In Chapter 3, the synthesis and reactivity of [ONO]NbMe2 and the reactivity of reduced species of [ONO]V(L)n are discussed.
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